Slony-I is a "master to multiple slaves" replication system supporting cascading (e.g. - a node can feed another node which feeds another node...) and failover for PostgresSQL. Slony replication is included in the Postgres Plus product suite.
The big picture for the development of Slony-I is that it is a master-slave replication system that includes all features and capabilities needed to replicate large databases to a reasonably limited number of slave systems.
Slony-I is a system designed for use at data centers and backup sites, where the normal mode of operation is that all nodes are available.
A fairly extensive "admin guide" comprising material in the CVS tree may be found here.
The original design document is available here. The main Slony-I project is available at www.slony.info